"Hoist That Rag" by Tom Waits
Greatness begins at when the guitar properly kicks in with a lengthy solo. Excellent guitar work from Marc Ribot as usual, who seems to be able to make anything he plays sound horribly atonal and distantly foreign-sounding even though he's hitting perfectly good notes. Live, here:
http://www.youtube.com/watch?v=W0kacLLT248 I urge you to listen.
"All You Can Do" by Willy Mason
Great beginning. Acoustic plays the riff a couple times, then the drums and electric guitar kick in with it. Powerful blues.
"Dang" by Jon Spencer Blues Explosion
The "DANG! Shine on.." that leads into the raucous and distorted harmonica solo and then the equally horrendous chorus. This is on youtube, you won't regret it:
http://www.youtube.com/watch?v=KgkEw4GjtdU